Advanced Materials & Manufacturing – Khalifa University /ar/ Tue, 21 Apr 2020 07:34:57 +0000 ar hourly 1 https://wordpress.org/?v=6.9.4 /wp-content/uploads/2019/09/cropped-favicon-32x32.jpg Advanced Materials & Manufacturing – Khalifa University /ar/ 32 32 Achieving Enhanced Radiative Properties for Semiconductors by Surface Modification via Ion Implantation /ar/research-field/achieving-enhanced-radiative-properties-for-semiconductors-by-surface-modification-via-ion-implantation Tue, 21 Apr 2020 07:34:57 +0000 /research-field/achieving-enhanced-radiative-properties-for-semiconductors-by-surface-modification-via-ion-implantation/ Surface modification and creation of specific interfaces are ubiquitous in almost all engineered semiconductor devices. These modifications are mainly obtained by the introduction of dopants into the semiconductor body by thermal diffusion, ion implantation, or ion-beam mixing of surface coatings with the semiconductor substrate. Due to the great importance of silicon as the material comprising …

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Surface modification and creation of specific interfaces are ubiquitous in almost all engineered semiconductor devices. These modifications are mainly obtained by the introduction of dopants into the semiconductor body by thermal diffusion, ion implantation, or ion-beam mixing of surface coatings with the semiconductor substrate. Due to the great importance of silicon as the material comprising 95% of all electronic devices, coupled with its inferior radiative properties, this project focuses on silicon materials and structures. The research will follow with other group IV semiconductors such as germanium or alloys of SiC or SiGe. In depth investigation of several ion implantation and ion-beam mixing schemes that varies from shallow to deep implantations, ion-beam mixing of co-evaporated/co-sputtered coatings, and inclusion of optically active impurities such as rare-earth metals will be performed. Preliminary results using ion-beam mixing of erbium and silicon; and erbium and silicon and germanium in silicon show that reasonably high 4f emission from Er+3 are attainable, while other results of dislocation defects engineered by implantation of boron corroborated with results from shallow boron ion implantation have both yielded band-to-band radiative carrier recombination of high efficiency.

These studies are remarkable for offering a circumvention of obstacles to optimal emission dictated by the indirect band gap nature of group IV semiconductors in general and crystalline Si in particular at various emission wavelengths. The proposed research will concentrate on optimum conditions for dopants to modify band gap of Si and indirect band gap semiconductors to favor radiative carrier recombination over heat generation non-radiative ones. The goals of this ambitious research are to explore the best mechanisms for dopants to modulate the band gap of Si; thus, controlling the dynamic electronic properties in devices established around the implanted region or modified surfaces, supported strongly by collaborators such as the SANDIA National Laboratories facility in New Mexico, USA and other interested collaborating scientists without any cost to the project.

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Bioinspired Passive Solar Desalination Empowered by Micro-3D Printing /ar/research-field/bioinspired-passive-solar-desalination-empowered-by-micro-3d-printing Tue, 21 Apr 2020 07:29:01 +0000 /research-field/bioinspired-passive-solar-desalination-empowered-by-micro-3d-printing/ The UAE has abundant solar energy source with an average radiation of 6.3 kWh/m2 per day. Solar steam generation is emerging as a promising technology for its potential in harvesting solar energy for various applications such as power generation, water treatment, desalination, and sterilization. Inspired by the natural desalination process of halophytes of the UAE, …

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The UAE has abundant solar energy source with an average radiation of 6.3 kWh/m2 per day. Solar steam generation is emerging as a promising technology for its potential in harvesting solar energy for various applications such as power generation, water treatment, desalination, and sterilization. Inspired by the natural desalination process of halophytes of the UAE, different from energy intensive RO/thermal desalination, we propose an all鈥恑n-one multifunctional 3D printed passive solar distillation device.

The capability of grey mangroves (Avicennia marina), the only species present in the UAE to repel 60鈥80% salt in roots, and unexplored mechanism of seawater propagation in Salicornia (S. bigelovii), motivate us to understand the morphological microstructures and quantify the role of each part of plant towards natural passive desalination. Recent advances in micro 3D printing enable us to print artificial leaves, stems, and roots at a very high resolution comparable to the microstructures of halophytes. These 3D printed artificial leaves, stems, and roots, with controlled surface chemistry and microstructures, empower us to perform mechanistic study systematically. This also leads us to design synthetic plants with high鈥恜erformance solar thermal energy conversion efficiency, owing to the insightful understanding of the phenomena: (i) sunlight harvesting of absorber surface like leaves; (ii) liquid propagation in superhydrophilic hierarchical microchannels as in stem; and (iii) salt repelling microchannels as in roots; ultimately leading towards vapor condensation and freshwater collection.

The proposed approach is valuable to both large鈥恠cale distillation and portable applications in rural areas or off鈥恎rid islands. The ability to generate vapor and collect fresh water under ambient sunlight passively holds promise for significant cost reduction of existing solar thermal systems while opening up new applications such as desalination, wastewater treatment, and sterilization. The scope of the proposed work is well aligned with one of the strategic research categories of AARE: energy, water, and environment.

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Design Principles for Thermoelectric Materials Based on 2D Heterostructures /ar/research-field/design-principles-for-thermoelectric-materials-based-on-2d-heterostructures Tue, 21 Apr 2020 07:26:22 +0000 /research-field/design-principles-for-thermoelectric-materials-based-on-2d-heterostructures/ Thermoelectric devices to generate electricity from waste heat have great potential in solving the world鈥檚 energy crisis. The development of efficient devices, however, requires materials with strong thermoelectric response. Two-dimensional (2D) transition metal dichalcogenides (TMDCs) are semiconductors with favorable electronic properties, while a high thermal conductivity limits their performance. Building heterostructures of different 2D materials …

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Thermoelectric devices to generate electricity from waste heat have great potential in solving the world鈥檚 energy crisis. The development of efficient devices, however, requires materials with strong thermoelectric response. Two-dimensional (2D) transition metal dichalcogenides (TMDCs) are semiconductors with favorable electronic properties, while a high thermal conductivity limits their performance. Building heterostructures of different 2D materials makes it possible to tune the phonon scattering and, therefore, reduce the thermal conductivity. In addition, such stacking modifies the electronic properties, which opens potential for further enhancement of the thermoelectric response.

The present project aims at establishing design principles for thermoelectric materials based on 2D heterostructures. It is planned to study heterostructures of different TMDCs, as well as heterostructures comprising TMDCs and other 2D materials. The interdependency between the chosen component materials and the thermoelectric behavior will be investigated in detail. In addition, the effects of intercalation of metal ions or dielectric layers in the van der Waals gap of the heterostructures will be addressed in order to evaluate whether intercalation can be an efficient tool for materials design. Computer simulations based on first-principles calculations and Boltzmann transport theory will be employed to tackle these tasks. For a reliable prediction of the thermoelectric properties, both the van der Waals interaction and spin-orbit coupling will be taken into consideration.

The proposed project will help identify efficient thermoelectric materials and provide atomic level understanding of the physics and chemistry determining the thermoelectric properties of 2D heterostructures. Progress in thermoelectric technology makes it possible to reduce the consumption of fossil fuels by increasing the contribution of green resources to the national energy mix. The proposal is aligned with the UAE Energy Strategy 2050, which targets that about 44% energy should be produce through clean energy.

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More Smart and Well-connected Advanced Composites for Next-generation Aircraft Structures (ARIC) /ar/research-field/more-smart-and-well-connected-advanced-composites-for-next-generation-aircraft-structures-aric Tue, 21 Apr 2020 07:22:06 +0000 /research-field/more-smart-and-well-connected-advanced-composites-for-next-generation-aircraft-structures-aric/ The notion of industry 4.0 is all about the well-connectivity and smartness of the industry and its response to the needs of the society. The application of graphene towards smart and well-connected products, particularly in aerospace, is increasing due its excellent intrinsic characteristics such as higher electrical and thermal conductivity, in addition to higher strength …

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The notion of industry 4.0 is all about the well-connectivity and smartness of the industry and its response to the needs of the society. The application of graphene towards smart and well-connected products, particularly in aerospace, is increasing due its excellent intrinsic characteristics such as higher electrical and thermal conductivity, in addition to higher strength and lighter weight. The European Union, under its one of the biggest scientific initiatives 鈥楪raphene Flagship,鈥 invested 1 billion euros in exploring the applications of graphene in next-generation products, and the investment is increasing rigorously over the years after the demonstration of promising results shown by graphene.

Till date, graphene has been predominantly used for sensors and thermal management, but its installation in load bearing aero-structures have not been explored yet in spite of its superlative mechanical properties. Designers can exploit a combination of properties of interest to realize a single multifunctional component using graphene. For instance, a single part based on the graphene can act as a structural component, while at the same time as a heat sink and/or an electrical sensor. The multi-functionality of a single part, as a result, will minimize the number of parts required and also will simplify the manufacturing cycle.

The proposed research aims to develop multifunctional load bearing aero-structures for next-generation aircrafts. This will be a step forward toward the future of aircrafts, which shall be more smart, more electric, and well-connected with higher sensing capabilities. The findings of this research will bring advancement to Abu Dhabi鈥檚 aerospace technological know-how in terms of using smart aircraft structures with sufficient structural integrity in combination with higher sensing, which is one of the strategic priority areas of the Emirate of Abu Dhabi. The smart composite structure will be able to monitor its health condition while in service, and will provoke preventive maintenance measures of the aero-structural components that could possibly avoid catastrophic, non-alarming failure. The project will join the forces of its multi-disciplinary faculty and young Emirati researchers, highlighting Abu Dhabi鈥檚 strategic priority in manufacturing, aerospace, and other critical national and global needs.

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Bend-dominated Mechanical Metamaterials with High Specific Strength and Stiffness Enabled by Additive Manufacturing /ar/research-field/bend-dominated-mechanical-metamaterials-with-high-specific-strength-and-stiffness-enabled-by-additive-manufacturing Tue, 21 Apr 2020 07:18:35 +0000 /research-field/bend-dominated-mechanical-metamaterials-with-high-specific-strength-and-stiffness-enabled-by-additive-manufacturing/ Mechanical metamaterials are synthetic materials whose mechanical properties are governed primarily by the architecture of their intricate cellular or porous microstructure, and not by their chemical composition. In 2018, the global metamaterials market size was $448 million, and is expected to grow to $1.8 billion by 2023 at a compound annual growth rate of 32%. …

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Mechanical metamaterials are synthetic materials whose mechanical properties are governed primarily by the architecture of their intricate cellular or porous microstructure, and not by their chemical composition. In 2018, the global metamaterials market size was $448 million, and is expected to grow to $1.8 billion by 2023 at a compound annual growth rate of 32%. Mechanical metamaterials are seen as critical enablers for lightweight structural applications that require not only high stiffness and strength but also possess additional built-in functionalities such as enhanced heat transfer, energy absorption, and programmable shape morphing features.

Here, we propose to develop a novel strategy for the design and fabrication of geometrically tailored mechanical metamaterials with enhanced specific strength, stiffness, and energy absorption capacity. By combining detailed finite element calculations with a heuristic optimization scheme, we will design unit cells with geometrically tailored structural features that maximize the specific strain energy storage in bend-dominated cellular networks. State-of-the-art 3D printing technology will be used to fabricate the geometrically tailored lattice designs developed in this project, and their mechanical properties will be experimentally evaluated and benchmarked against already existing stretch and bend dominated metamaterials.

The project will have a broader impact on the UAE society and economy by providing a superb research platform that will enable the development of innovative engineering systems for the future of the nation鈥檚 economic growth, particularly in the Aerospace and Defense sector. Furthermore, the project will strongly contribute to the development of human capital through training and mentoring of graduate students and provide promising potential for the generation of intellectual property and technology transfer to the industry.

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Ultra-lightweight Cellular Solids of Two-dimensional Heterogeneous Materials for EMI Shielding, Lightening Protection, and Mechanical Wave Suppression /ar/research-field/ultra-lightweight-cellular-solids-of-two-dimensional-heterogeneous-materials-for-emi-shielding-lightening-protection-and-mechanical-wave-suppression Tue, 21 Apr 2020 07:14:57 +0000 /research-field/ultra-lightweight-cellular-solids-of-two-dimensional-heterogeneous-materials-for-emi-shielding-lightening-protection-and-mechanical-wave-suppression/ We propose to develop novel, ultra-lightweight, multifunctional cellular solids (i.e., foams or sponge) utilizing two-dimensional heterogeneous materials also known as van der Waals heterogeneous structures (VDWHSs). These are multi-layered, atomic-thin materials composed of different types of base-materials, like a stack of papers of different colors where each colored sheet represent a specific material, in conjunction …

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We propose to develop novel, ultra-lightweight, multifunctional cellular solids (i.e., foams or sponge) utilizing two-dimensional heterogeneous materials also known as van der Waals heterogeneous structures (VDWHSs). These are multi-layered, atomic-thin materials composed of different types of base-materials, like a stack of papers of different colors where each colored sheet represent a specific material, in conjunction with advanced 3D-printing technologies. The intended applications are for electromagnetic interference (EMI) shielding, such as stealthiness under radar, lightening protection for unmanned aerial vehicles (UAVs), and marine surface vehicles, as well as mechanical vibration suppression for underwater vehicles. The technology will have wider implications for national defense.

The core technological innovation is to find one or more VDWHS systems with high electrical conductivity and put this material to form cellular solids where its internal microstructure is optimized by design for electromagnetic wave shielding and for mechanical wave suppression. The optimized scaffold of internal structure is produced by 3D printing and later removed after coating with VDWHS, leaving a cellular solid of purely VDWHS. We will address two key research challenges: (a) to design, synthesize, and characterize novel VDWHSs; and (b) to design, develop, and characterize cellular solids made of VDWHS for the aforementioned aims. At the conclusion of the project, we expect to deliver a novel technology for producing a material with high effectiveness for EMI shielding, lightening protection, as well as for mechanical vibration suppression with designated band gaps. In addition, we will be training a few Emirati students at the undergraduate and master level and produce three to four technical papers in leading international journals.

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Low-temperature PEM Fuel Cell Modeling /ar/research-field/low-temperature-pem-fuel-cell-modeling Tue, 21 Apr 2020 07:10:24 +0000 /research-field/low-temperature-pem-fuel-cell-modeling/ Low-temperature Polymer Electrolyte Membrane Fuel Cell (PEMFC) is an electrochemical device that ensures the generation of electricity from a chemical reaction between hydrogen and oxygen. This technology has been the focus of research and development because of its sustainable nature and zero gas emissions as compared to fossil fuels, but is still far from maturity. …

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Low-temperature Polymer Electrolyte Membrane Fuel Cell (PEMFC) is an electrochemical device that ensures the generation of electricity from a chemical reaction between hydrogen and oxygen. This technology has been the focus of research and development because of its sustainable nature and zero gas emissions as compared to fossil fuels, but is still far from maturity. Its efficiency and power-to-weight ratio are still below the desired levels and improvement of these characteristics would be high value, increasing reliability, and the range of application areas for this technology. The project scope includes: (i) development of a detailed non-linear model of the PEM fuel cell, particularly using the approaches to the modeling of complex electrical and thermo-dynamic components developed within the process control group of the Khalifa University; (ii) development and design of the model-based control of PEM fuel cell system; (iii) implementation of the complete system and experimental testing.

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Processing for Efficient Band-gap Emission from Silicon Interfaced with Sol-gel Films /ar/research-field/processing-for-efficient-band-gap-emission-from-silicon-interfaced-with-sol-gel-films Tue, 21 Apr 2020 07:09:06 +0000 /research-field/processing-for-efficient-band-gap-emission-from-silicon-interfaced-with-sol-gel-films/ This project investigates photonic structures with novel functions fabricated by interfacing sol-gel films with crystalline silicon surfaces. Preliminary results using erbium-doped films show that this combination yields high emission levels for band-gap radiation from the silicon has disclosed an unexpected property of photonic materials. This is significant for surmounting obstacles to emission posed by the …

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This project investigates photonic structures with novel functions fabricated by interfacing sol-gel films with crystalline silicon surfaces. Preliminary results using erbium-doped films show that this combination yields high emission levels for band-gap radiation from the silicon has disclosed an unexpected property of photonic materials. This is significant for surmounting obstacles to emission posed by the indirect band gap nature of crystalline Si, where free carriers usually recombine non-radiative generating heat rather than photons.

The proposed research aims to elucidate the physical mechanism responsible for the enhanced emission and to determine structures for producing optimal quantum efficiencies. It will build on evidence that the emission of band-gap photons is promoted by non-uniform elastic strains in the silicon near the interface adjacent to a sol-gel film containing non-uniform stresses. The theoretical framework posits that carrier localization within such strain fields enhances radiative recombination in silicon by increasing electron-hole interactions.

The experimental approach is to use test structures processed on Si and sili卢con-on-insulator (SOI) material for improved optical and electronic isolation and resolution. Experimental techniques for studying relevant aspects of the materials and photonics science are specifically: excitation-matrix photoluminescence, lifetime measurements, emission depth profiling, strain measurement by X-ray diffraction and micro-Raman spectroscopy, infrared spectroscopy, MOS capacitor analysis, and electrical transport. Sol-gel film study encompasses its formulation chemistry and cation doping with species both optically active and not.

The goal of this research is to characterize the optically active region in the silicon, indicated to lie adjacent to the interface with the sol-gel film, and quantifying internal and external emission quantum efficiencies. Relating film composition and mechanics to optical modifications of the adjacent silicon will also be fully explored.

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Highly Efficient Nanoporous Antibacterial Hybrids /ar/research-field/highly-efficient-nanoporous-antibacterial-hybrids Tue, 21 Apr 2020 07:05:19 +0000 /research-field/highly-efficient-nanoporous-antibacterial-hybrids/ Increased proliferation of antimicrobial-resistant and new strains of bacterial pathogens severely impact the current health, environmental, and technological developments. A recent study predicted that if the trend continues at the current speed, by 2050 more people will die because of drug-resistant infections than cancer. In Abu Dhabi and the UAE, the phenomenon is even more …

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Increased proliferation of antimicrobial-resistant and new strains of bacterial pathogens severely impact the current health, environmental, and technological developments. A recent study predicted that if the trend continues at the current speed, by 2050 more people will die because of drug-resistant infections than cancer. In Abu Dhabi and the UAE, the phenomenon is even more intense with climate conditions enhancing rapid growth and spread of pathogenic microorganisms. Indicatively, a recent study commented by the The National newspaper found a 鈥渉eavy growth鈥 of the potentially deadly E. coli bug and other dangerous bacteria in Abu Dhabi, even on common work surfaces, while the prolonged use of air conditioning was found to often cause extensive fungal growth. From a technological point of view, uncontrollable bacteria proliferation/biofouling on surfaces of industrial interest in Abu Dhabi, including desalination, oil & gas processing, water treatment, and food processing, cause a serious loss of productivity, compromised quality, huge amounts of energy spent, and high costs. To this extent, the design of novel and highly efficient antibacterial agents is urgently needed.

Nanotechnology can offer unique opportunities for bottom-up development of novel bacteriostatic and bactericidal formulations. The unique bactericidal effect of nanoparticles is attributed to their small size and high surface to volume ratio, which allows them to interact closely with microbial membranes. Our recent work resulted in the development of very efficient nanostructured antibacterial agents based on graphene with bimetallic loadings while it was recently expanded with the development of novel nanostructured agents consisting of stabilized metallic species in pure ionic form that exhibited an even higher antibacterial efficacy.

The objective of the ADEK project is to build upon this prior developments and investigate the growth of highly efficient agents based on bi-metallic of multi-metallic loadings using properly engineered, high surface area porous supports, able to bound metallic species in nanoparticle but also in ionic forms. This will be combined with the expertise and capability of the group to design, modify, functionalize, and customize a variety of nanomaterials and porous nanostructures toward the development of the next-generation of antimicrobial agents.聽

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Hydrogen Embrittlement of Aluminum Alloys /ar/research-field/hydrogen-embrittlement-of-aluminum-alloys Mon, 20 Apr 2020 07:59:55 +0000 /research-field/hydrogen-embrittlement-of-aluminum-alloys/ The post Hydrogen Embrittlement of Aluminum Alloys appeared first on 今日吃瓜.

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Additive Manufacturing in Spare Parts Logistics /ar/research-field/additive-manufacturing-in-spare-parts-logistics Mon, 20 Apr 2020 07:54:28 +0000 /research-field/additive-manufacturing-in-spare-parts-logistics/ The post Additive Manufacturing in Spare Parts Logistics appeared first on 今日吃瓜.

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Metal-matrix Nanocomposites of Born Nitride Nanotubes /ar/research-field/metal-matrix-nanocomposites-of-born-nitride-nanotubes Mon, 20 Apr 2020 07:51:50 +0000 /research-field/metal-matrix-nanocomposites-of-born-nitride-nanotubes/ The post Metal-matrix Nanocomposites of Born Nitride Nanotubes appeared first on 今日吃瓜.

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